'From C++ to Objective-C' is also good eBook. http://pierre.chachatelier.fr/programmation/fichiers/cpp-obj...
I also bought 'Cocoa Programming for Mac OS X' http://www.amazon.com/Cocoa-Programming-Mac-3rd-Edition/dp/0...
Cocoa is quite different than anything I had programmed before. Once I wrapped my head around nibs, IBOutlets and IBActions it was fairly easy. Once I got going, the apple developer docs were all I needed, but learning I found easier to do from a book than the docs.
Unfortunately, it doesn't really make the learning curve any less intense. While Objective-C's syntax and style are somewhat difficult, the real challenge to Mac/iOS programming is having a working knowledge of the Cocoa API. MacRuby simply acts as a bridge between Ruby and Cocoa, meaning you need to know exactly the same amount about API methods no matter the programming language you choose.
Reading the currently available MacRuby book is a great idea - http://ofps.oreilly.com/titles/9781449380373/. If you find yourself confused by the concepts, you should try learning Objective-C and Cocoa first (I learned with http://www.amazon.com/Cocoa-Programming-Mac-OS-3rd/dp/032150...). It is certainly possible to dive in with MacRuby! Just remember that it's not 1.0 yet, and could present technical difficulties in unexpected ways. Otherwise, it's super fun!
[1] http://www.amazon.com/Cocoa-Programming-Mac-COCOA-PROGRAMMIN...
http://www.amazon.com/Cocoa-Programming-Mac-OS-3rd/dp/032150...
Part of the problem was that I didn't know C at all. Recently I decided to have another go at it, so I read the first chapter of K&R and did all the exercises, then read a few of the other chapters (2, 5, and 6 I believe). After that, I read this book: http://www.apress.com/book/view/1430218150 . "Learn Objective-C on the Mac" has been great - it's readable, good-humored, succinct, and comprehensive. It's answered all the remaining questions I still had about ObjC and I finally feel like I get the language.
If you've ever wanted to write that little iPhone app, pick up his book and you'll be a pro in few months.
Having read their Cocoa programming for OS X book (http://www.amazon.com/Cocoa-Programming-Mac-3rd-Edition/dp/0...), I can wholeheartedly recommend their books.