It's probably best to start with a small project and tackle one project after the other.
I also read this book which helped since it tackled all the basics that one needs to know for a full Mac app. It's german only though (http://www.amazon.de/Objective-C-Cocoa-Nachfolger-Tiger-XCod...) alternatively the aforementioned Hillegas (http://www.amazon.com/Objective-C-Programming-Ranch-Guide-Gu...) which is really good.
Also if you're looking for a good book about iOS http://www.amazon.com/gp/aw/d/1430236051/ref=redir_mdp_mobil...
For learning the ins and out of objective c I've heard this is a good book: http://www.amazon.com/gp/aw/d/0321706285
Good luck!
Having read their Cocoa programming for OS X book (http://www.amazon.com/Cocoa-Programming-Mac-3rd-Edition/dp/0...), I can wholeheartedly recommend their books.