It's a fascinating story, and covers a lot of the science behind breathing techniques, how our autoimmune system works, and step-by-step process to take advantage yourself.
ps: if you want a TL;DR, here's an interview [3] with Scott that summarizes the book well.
[1] https://www.amazon.com/What-Doesnt-Kill-Environmental-Condit...
[2] https://en.wikipedia.org/wiki/Wim_Hof
[3] https://www.dragondoor.com/interview_with_scott_carney_autho...
I've mentioned the book on several other threads [2], so I'll avoid repeating here.
Along the same lines of expanding the ability of your body/mind, one that I'm currently reading is "What doesn't kill us" [3]. Pretty fascinating to think that we have a lot more control over our immune system than originally thought.
[1] https://www.amazon.com/Why-We-Sleep-Unlocking-Dreams/dp/1501...
[2] https://news.ycombinator.com/item?id=17606274
[3] https://www.amazon.com/What-Doesnt-Kill-Environmental-Condit...
It was written by an investigative journalist that was initially skeptic of the method, and decided to debunk the myth.
[1] What Doesn't Kill Us: How Freezing Water, Extreme Altitude, and Environmental Conditioning Will Renew Our Lost Evolutionary Strength
https://www.amazon.com/What-Doesnt-Kill-Environmental-Condit...